Direct evidence for enzyme persulfide and disulfide intermediates during 4-thiouridine biosynthesis.

Chem. Commun. (Camb.). 2006 Aug 7(29):3104-6. doi:10.1039/b604040c. Epub 2006 Jun 14

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摘要

Two proposed mechanisms for 4-thiouridine generation share key cysteine persulfide and disulfide intermediates, and indirect evidence of their existence has been previously reported; chemical trapping and mass spectrometry have now provided direct and definitive evidence of these key intermediates.

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Direct evidence for enzyme persulfide and disulfide intermediates during 4-thiouridine biosynthesis.

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